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Bianca has her real full name as Odinakachukwu Olivia Odumegwu-Ojukwu. She is a beautiful Nigerian politician, diplomat, lawyer, businesswoman and beauty pageant titleholder and widow of former Biafra leader, Chukwuemeka Odumegwu Ojukwu. Bianca was born on August 5, to the former of governor of Anambra State, C. Onoh and the sixth child in the family.

Her mother Carol, was a college principal. She thereafter began a combined honours degree in Politics, Economics and Law at the University of Buckingham. Upon graduation, she attended the Nigerian Law School and was eventually called to the bar after which she joined the family business.

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She set up a Cosmetics business Bianca Blend and her interior decorating outfit Mirabella and fronted print commercials for her brand. She also established the non-government organization, Hope House Trust, centred towards rehabilitating juvenile offenders in Enugu. She also recorded huge success when she became the first African to win Miss Intercontinental that same year, and was named Miss Congeniality at the now defunct Miss Charm International in Russia where she was also a semi-finalist.

Bianca Odemegwu has founded several charitable organizations, including Hope House Trust, which focuses on rehabilitating juvenile offenders. This controversial romance did not augur well the beauty pageant as it almost ruined her relationship with her father in the early s. The immense pressure of being under the public eye became increasingly unbearable, causing her to resign as Miss Intercontinental as her main concern was completing her education as a law student.

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In , despite the controversies that surrounded their relationship, Bianca eventually married the former Biafran leader in an elaborate wedding ceremony held in Abuja, the federal capital territory of Nigeria. In , following the death of her husband, his will, which left most of his assets to her, generated a great deal of controversy and disaffection among several family members.

The outgoing first lady of Anambra State had physically attacked her at the state function.